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  1. Abstract

    Catalyst impregnation is the first step and one of the most crucial steps for preparing industrial catalysts. The process is typically performed in rotating vessels with a spray-nozzle to distribute the liquid onto porous catalyst supports until the pore volume is reached. The inter-particle variability of the impregnated liquid inside the particles significantly affects the activity and selectivity of the resulting catalyst. Current scale-up practices lead to poor fluid distribution and inhomogeneity in the liquid content. The aim of this work is to understand the dynamic behavior of the particles under the spray nozzle, which is essential for desired content uniformity, and to develop a scale-up model for the dry impregnation process. In this work, we considered four dimensionless numbers in the scaling analysis. The scale-up rules require that the dimensionless numbers are kept constant for different scales. Both DEM simulations and matching experiments of dry impregnation inside the porous particles were performed for different vessel sizes. The water content of the particles was compared for different times and locations, and the relative standard deviation is calculated from the axial water content. Simulation and experimental results show that particles achieve similar content uniformity at the end of impregnation, confirming that the scale-up rules are applicable to all vessel sizes. The dimensionless numbers give very good scale-up performance since curves collapse indicating similarity in the processes. In addition, the scale-up method is validated for different particle sizes in simulations.

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  2. Abstract

    Abrupt variations of auroral electrojets can induce geomagnetically induced currents, and the ability to model and forecast them is a pressing goal of space weather research. We report an auroral electrojet spike event that is extreme in magnitude, explosive in nature, and global in spatial extent that occurred on 24 April 2023. The event serves as a fundamental test of our understanding of the response of the geospace system to solar wind dynamics. Our results illustrate new and important characteristics that are drastically different from existing knowledge. Most important findings include (a) the event was only of ∼5‐min duration and was limited to a narrow (2°–3°) band of diffuse aurora; (b) the longitudinal span covered the entire nightside sector, possibly extending to the dayside; (c) the trigger seems to be a transient solar wind dynamic pressure pulse. In comparison, substorms usually last 1–2 hr and span almost the entire latitudinal width of the auroral oval. Magnetic perturbation events (MPEs) span hundreds km in radius. Both substorms and MPEs are mainly driven by disturbances in the magnetotail. A possible explanation is that the pressure pulse compresses the magnetosphere and enhances diffuse precipitation of electrons and protons from the inner plasma sheet, which elevates the ionospheric conductivity and intensifies the auroral electrojet. Therefore, the event exhibits a potentially new type of geomagnetic disturbance and highlights a solar wind driver that is enormously influential in driving extreme space weather events.

     
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  3. Abstract

    Low‐altitude observations of magnetospheric particles provide a unique opportunity for remote probing of the magnetospheric and plasma states during active times. We present the first statistical analysis of a specific pattern in such observations, energetic electron flux dropouts in the low‐altitude projection of the plasma sheet. Using 3.5 years of data from the ELFIN CubeSats we report the occurrence distribution of 145 energetic electron flux dropout events and identify characteristics, including their prevalence in the dusk and premidnight sectors, their association with substorms and enhanced auroral activities, and their correlation with the region‐1 (R1) field‐aligned current region. We also investigate three representative dropout events which benefit from satellite conjunctions between ELFIN, GOES, and THEMIS, to better understand the magnetospheric drivers and magnetic field conditions that lead to such dropouts as viewed by ELFIN. One class of dropouts may be associated with magnetic field mapping distortions due to local enhancements and thinning of cross‐tail current sheets and amplification of R1 field‐aligned currents. The other class may be associated with the increase in perpendicular anisotropy of magnetospheric electrons due to magnetic field dipolarizations near premidnight. These plasma sheet flux dropouts at ELFIN provide a valuable tool for refining magnetospheric models, thereby improving the accuracy of field‐line mapping during substorms.

     
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  4. Abstract

    Energetic (≳50 keV) electron precipitation from the magnetosphere to the ionosphere during substorms can be important for magnetosphere‐ionosphere coupling. Using conjugate observations between the THEMIS, ELFIN, and DMSP spacecraft during a substorm, we have analyzed the energetic electron precipitation, the magnetospheric injection, and the associated plasma waves to examine the role of waves in pitch‐angle scattering plasma sheet electrons into the loss cone. During the substorm expansion phase, ELFIN‐A observed 50–300 keV electron precipitation from the plasma sheet that was likely driven by wave‐particle interactions. The identification of the low‐altitude extent of the plasma sheet from ELFIN is aided by DMSP global auroral images. Combining quasi‐linear theory, numerical test particle simulations, and equatorial THEMIS measurements of particles and fields, we have evaluated the relative importance of kinetic Alfvén waves (KAWs) and whistler‐mode waves in driving the observed precipitation. We find that the KAW‐driven bounce‐averaged pitch‐angle diffusion coefficientsnear the edge of the loss cone are ∼10−6–10−5s−1for these energetic electrons. Thedue to parallel whistler‐mode waves, observed at THEMIS ∼10‐min after the ELFIN observations, are ∼10−8–10−6s−1. Thus, at least in this case, the observed KAWs dominate over the observed whistler‐mode waves in the scattering and precipitation of energetic plasma sheet electrons during the substorm injection.

     
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  5. Abstract

    Man‐made very low frequency (VLF) transmitter waves play a critical role in energetic electron scattering and precipitation from the inner radiation belt, a type of which is called wisp precipitation. Wisps exhibit dispersive energy‐versus‐Lspectra due to the evolution of electron cyclotron resonance conditions with near‐monochromatic VLF transmitter waves. Here, we report on such observations of inner belt wisp precipitation events with full pitch angle resolution in the energy range of 50 to ∼500 keV as measured by Electron Loss and Fields Investigation (ELFIN) atL < ∼2 between March 2021 and April 2022. Statistical observations (82 events) reveal occasional (18 events) wisp precipitation events with local bounce‐loss‐cone electron flux enhancements, which provide new information compared with flux enhancements measured in previous studies only in the drift loss cone. Based on magnetic field and plasmaspheric density models, quasilinear theory, and detailed pitch angle distributions of wisps from ELFIN, we have estimated the wisp electron bounce‐averaged pitch angle diffusion coefficients to be of the order of 10−4to 10−2 s−1. These are several orders of magnitude larger than the diffusion rates calculated from models using global statistical averages of VLF transmitter wave power. When using our estimated diffusion coefficients to deduce the associated local transmitter wave amplitudes near the equator, based on quasilinear calculations from a transmitter‐induced electron diffusion model, we find these wave amplitudes to be >1 mV/m. Although probable overestimates, such inferred wave amplitudes exceed the theoretical threshold amplitude for nonlinear interactions, strongly suggesting that it is necessary to include nonlinear effects for an accurate evaluation of energetic electron scattering by transmitter waves.

     
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  6. Abstract

    Electron injections are critical processes associated with magnetospheric substorms, which deposit significant electron energy into the ionosphere. Although wave scattering of <10 keV electrons during injections has been well studied, the link between magnetotail electron injections and energetic (≥100 keV) electron precipitation remains elusive. Using conjugate observations between the Electron Loss and Fields Investigation (ELFIN) and Magnetospheric Multiscale (MMS) missions, we present evidence of tens to hundreds of keV electron precipitation to the ionosphere potentially driven by kinetic Alfvén waves (KAWs) associated with magnetotail electron injections and magnetic field gradients. Test particle simulations adapted to observations show that dipolarization‐front magnetic field gradients and associated ∇Bdrifts allow Doppler‐shifted Landau resonances between the injected electrons and KAWs, producing electron spatial scattering across the front which results in pitch‐angle decreases and subsequent precipitation. Test particle results show that such KAW‐driven precipitation can account for ELFIN observations below ∼300 keV.

     
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  7. Abstract

    Plasma sheet electron precipitation into the diffuse aurora is critical for magnetosphere‐ionosphere coupling. Recent studies have shown that electron phase space holes can pitch‐angle scatter electrons and may produce plasma sheet electron precipitation. These studies have assumed identical electron hole parameters to estimate electron scattering rates (Vasko et al., 2018,https://doi.org/10.1063/1.5039687). In this study, we have re‐evaluated the efficiency of this scattering by incorporating realistic electron hole properties from direct spacecraft observations into computing electron diffusion rates and lifetimes. The most important electron hole properties in this evaluation are their distributions in velocity and spatial scale and electric field root‐mean‐square intensity (). Using direct measurements of electron holes during a plasma injection event observed by the Van Allen Probe at, we find that when4 mV/m electron lifetimes can drop below 1 h and are mostly within strong diffusion limits at energies below10 keV. During an injection observed by the THEMIS spacecraft at, electron holes with even typical intensities (1 mV/m) can deplete low‐energy (a few keV) plasma sheet electrons within tens of minutes following injections and convection from the tail. Our results confirm that electron holes are a significant contributor to plasma sheet electron precipitation during injections.

     
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  8. Abstract

    Plasma sheet electron precipitation is critical in magnetosphere‐ionosphere coupling and has long been attributed to electron scattering by whistler‐mode and electron cyclotron harmonic waves. Recent observations have revealed that time domain structures (TDSs) that appear as broadband electrostatic fluctuations may also scatter plasma sheet electrons. However, there has been no observational evidence of TDS scattering electrons into the ionosphere. This study presents potential evidence from conjugate observations between the Time History of Events and Macroscale Interactions during Substorms (THEMIS) mission and the low‐altitude Enhanced Polar Outflow Probe (e‐POP) spacecraft. During the five events presented, THEMIS observed intense electron injections accompanied by TDSs, while e‐POP captured precipitation of plasma sheet electrons with energies100–325 eV over a broad pitch angle range. The observed TDSs can efficiently scatter these electrons exceeding the strong diffusion limit. Our results suggest that TDSs may contribute to plasma sheet electron scattering around times of injections.

     
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  9. Abstract

    Whistler‐mode chorus waves are critical for driving resonant scattering and loss of radiation belt relativistic electrons into the atmosphere. The resonant energies of electrons scattered by chorus waves increase at increasingly higher magnetic latitudes. Propagation of chorus waves to middle and high latitudes is hampered by wave divergence and Landau damping but is promoted otherwise if ducted by density irregularities. Although ducting theories have been proposed since the 1960s, no conjugate observation of ducted chorus propagation from the equatorial magnetosphere to the ionosphere has been observed so far. Here we provide such an observation, for the first time, using conjugate spacecraft measurements. Ducted chorus waves maintain significant wave power upon reaching the ionosphere, which is confirmed by ray‐tracing simulations. Our results suggest that ducted chorus waves may be an important driver for relativistic electron precipitation.

     
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